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文章基本信息

  • 标题:Manganese-Catalyzed Oxophosphorylation Reaction of Carbon–Carbon Double Bonds Using Molecular Oxygen in Air
  • 作者:Daisuke Yamamoto ; Hiromasa Ansai ; Junichi Hoshino
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:2018
  • 卷号:66
  • 期号:9
  • 页码:873-879
  • DOI:10.1248/cpb.c18-00381
  • 语种:English
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:A novel aerobic manganese-catalyzed oxophosphorylation reaction of carbon–carbon double bonds of styrene derivatives and vinyl ethers using diethyl H -phosphonates was developed. This direct transformation of alkenes to β-ketophosphonate readily proceeded at room temperature via the direct incorporation of molecular oxygen present in air (open flask).
  • 关键词:oxophosphorylation;atmospheric oxygen;manganese catalyst;β-ketophosphonate
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