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  • 标题:Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface
  • 本地全文:下载
  • 作者:Brian H. Shen ; Gabriel M. Veith ; Wyatt E. Tenhaeff
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2018
  • 卷号:8
  • 期号:1
  • 页码:11549
  • DOI:10.1038/s41598-018-30000-z
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:. Electrochemical impedance spectroscopy performed on silicon electrodes showed that resistance from solid electrolyte interface formation increased from 79 to 1508 Ω in untreated silicon thin films over 26 cycles, while resistance growth was lower - from 98 to 498 Ω - in silicon films functionalized with PMMA brushes. The lower increase suggests enhanced surface passivation and lower electrolyte degradation. This work provides a pathway to develop artificial solid electrolyte interfaces synthesized under controlled reaction conditions.
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