摘要：originating from the biquadratic magnetostrictive interaction. With the help of ab initio calculations, we have numerically evaluated magnitudes of these improper polarizations, in addition to the estimate of all three relevant coupling constants. We further predict that the magnetic susceptibility increases substantially upon the transition from the bulk R3c BFO to the homogeneous canted spin state in a constrained epitaxial film, which satisfactorily accounts for the experimental observation. The present study will help us understand the magnetoelectric coupling and shed light on design of BFO-based materials with improved multiferroic properties.
