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  • 标题:Air-oxidation from sulfur to sulfone-bridged Schiff-base macrocyclic complexes showing enhanced antimicrobial activities
  • 本地全文:下载
  • 作者:Genfeng Feng ; Yunshan Shi ; Lei Zhang
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2017
  • 卷号:7
  • 期号:1
  • 页码:15881
  • DOI:10.1038/s41598-017-15898-1
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:Two embedded sulfur atoms in a novel [2 + 2] Schiff-base macrocyclic dinuclear Zn(II) complex were found to be easily autoxidized to the sulfone units on air exposure, and the resultant sulfone-functionalized macrocyclic complex was obtained by the post-modification strategy exhibiting enhanced antimicrobial activities because of the presence of dual active sites in comparison with the sulfur-containing Schiff-base macrocycle.
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