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  • 标题:Evaluation of Fatty Acid Waste in the Synthesis of Oligo(Ether-Ester)s
  • 本地全文:下载
  • 作者:S. Kocaman ; A. Cerit ; U. Soydal
  • 期刊名称:International Journal of Polymer Science
  • 印刷版ISSN:1687-9422
  • 电子版ISSN:1687-9430
  • 出版年度:2019
  • 卷号:2019
  • 页码:1-9
  • DOI:10.1155/2019/1519593
  • 出版社:Hindawi Publishing Corporation
  • 摘要:In this study, the waste of sunflower oil refinement was converted to a fatty acid glycidyl ester (FAGE). An unsaturated oligo(ether-ester) (OEE) was synthesized by ring-opening polymerization using propylene oxide (PO) and FAGE. Oligo(ether-ester) production was achieved with a high yield of 80% at 5 h and 0°C when the mole ratio of PO : FAGE was 1 : 1. Synthesized OEE was characterized by FTIR and several chemical analysis methods. According to the TGA results, ,, and values of OEE-styrene copolymers increased up to a 7 : 3 mole ratio then decreased. The weight losses of these copolymers changed in the range of 3-5%. The data of longitudinal and transversal wave velocities showed that copolymers with styrene had better elastic properties and impact resistances compared to those with pure polystyrene.
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