In addition to suitable organizational working environment effective management of human psychological capital has become very important for any organizational success in today’s complex business world. This study aims to investigate the relationship between organizational work environment, psychological capital and job satisfaction by using a sample of 176 employees from four departments of civil secretariat government of Balochistan. According to correlation and regression analysis there was significant statistical relationship between organizational work environment, psychological capital and job satisfaction. Employees with positive psychological capital are more satisfied from jobs if working in even less conducive environment.