Based on the Langmuir adsorption model, the adsorption constants of eighteen coal samples from the same coal mine with outburst risk, weak outburst risk, and non‐outburst risk were tested by high‐pressure capacity method under different temperature conditions. The results show that the adsorption constants a and b monotonically decrease with the increase in temperature. The relationship between a and temperature shows three stages: accelerated decreasing stage, decelerated decreasing stage, and stable stage. The b decreases with the increase in temperature also shows three stages, namely relative stability, slow decrease, and accelerated decrease. The a × b for the outburst coal seam decreases with increasing temperature, which is similar to b . The a × b for the weak and non‐outburst coal seams decreases with increasing temperature, which is similar to a . Furthermore, the a of the outburst coal seam decreases with the increase in temperature, and the decrease of b is the largest. The a of the weak and non‐outburst coal seams decreases with the increase in temperature, and the magnitude is relatively large. The b decreases slightly, with a smaller magnitude. The a × b of weak outburst seam is smaller than that of non‐outburst seam and is larger than that of outburst seam. The achievements can provide guiding significance for coal and gas outburst prevention and control.