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  • 标题:Fabrication of Pd NPs-supported porous carbon by integrating the reducing reactivity and carbon-rich network of lignin
  • 本地全文:下载
  • 作者:Guocheng Han ; Qimeng Jiang ; Weijie Ye
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2019
  • 卷号:9
  • 期号:1
  • 页码:1-9
  • DOI:10.1038/s41598-019-43840-0
  • 出版社:Springer Nature
  • 摘要:The renewable resource as a major feedstock to prepare porous carbon has showed many advantages compared to fossil-based materials. This study proposes a new strategy to synthesize palladium nanoparticles (Pd NPs)-supported porous carbon, utilizing both the chemical reactivity and the carbon-rich 3D network of lignin. The Pd NPs-supported porous carbons were prepared in one-pot synthesis, with Pd(NH 3 ) 2 Cl 2 as precursor, lignin as reducing and stabilizing agents of Pd NPs, nano SiO 2 as hard-template, followed by carbonization and removal of the template. The results reveal a positive effect of Pd precursor dosage on the development and excellent texture of the Pd NPs-supported porous carbon. Accordingly, the synthesized porous carbon was proved to have large micropore volume and good micro-mesopore porous structure, revealing it a promising hydrogen adsorbent.
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