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  • 标题:The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation
  • 本地全文:下载
  • 作者:Dong-Ping Tao
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2016
  • 卷号:6
  • 期号:1
  • DOI:10.1038/srep35792
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:In a multi-component homogeneous system, the relationship between partial molar and molar quantity (RPMQ) is proved to be an equivalent relation of the Gibbs-Duhem equation. The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation are inferred from the RPMQ. Based on the inference, an asymmetric regular solution model is suggested to deal with those systems that exhibit strong negative deviation, strong positive deviation, and both strong positive and negative deviation from ideality.
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