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  • 标题:Understanding hydrothermal transformation from Mn2O3 particles to Na0.55Mn2O4·1.5H2O nanosheets, nanobelts and single crystalline ultra-long Na4Mn9O18 nanowires
  • 本地全文:下载
  • 作者:Yohan Park ; Sung Woo Lee ; Ki Hyeon Kim
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2015
  • 卷号:5
  • 期号:1
  • DOI:10.1038/srep18275
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:Manganese oxides are one of the most valuable materials for batteries, fuel cells and catalysis. Herein, we report the change in morphology and phase of as-synthesized Mn2O3 by inserting Na+ ions. In particular, Mn2O3 nanoparticles were first transformed to 2 nm thin Na0.55Mn2O4·1.5H2O nanosheets and nanobelts via hydrothermal exfoliation and Na cation intercalation, and finally to sub-mm ultra-long single crystalline Na4Mn9O18 nanowires. This paper reports the morphology and phase-dependent magnetic and catalytic (CO oxidation) properties of the as-synthesized nanostructured Na intercalated Mn-based materials.
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