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  • 标题:Self-sorted Oligophenylvinylene and Perylene Bisimide Hydrogels
  • 本地全文:下载
  • 作者:Ana M. Castilla ; Emily R. Draper ; Michael C. Nolan
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2017
  • 卷号:7
  • 期号:1
  • DOI:10.1038/s41598-017-08644-0
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:We describe two component hydrogels with networks composed of self-sorted fibres. The component gelators are based on 1,4-distyrylbenzene (OPV3) and perylene bisimide (PBI) units. Self-sorted gels can be formed by a slow decrease in pH, which leads to sequential assembly. We demonstrate self-sorting by NMR, rheology and small angle X-ray scattering (SAXS). Photoconductive xerogels can be prepared by drying these gels. The wavelength response of the xerogel is different to that of the PBI alone.
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