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  • 标题:Direct physical vapor deposition and flexible photoelectrical properties of large-area free-standing films of metal octaethylporphyrin on ionic liquid surface
  • 本地全文:下载
  • 作者:Yan Xiao ; Feng-Xia Wang ; Jia-Mei Yang
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2017
  • 卷号:7
  • 期号:1
  • DOI:10.1038/s41598-017-10293-2
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:Free-standing films of metal octaethylporphyrins (MOEPs) were prepared for the first time by a physical vapor deposition on surface of an ionic liquid (IL). Different from those on solid surfaces, the as-obtained films were very compact and with plannar structure. The monitoring of time-dependent process indicated that the high surface energy of IL and the strong π…π interaction between MOEP molecules played key roles in forming such films. Furthermore, the as-obtained film showed good transferability, which made it possible to be easily transferred to any substrates for further device application. More importantly, the prototype photodetectors based on free-standing films of MOEP showed ultra flexibility, mechanical stability, and durability.
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