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  • 标题:Fabrication and characterisation of magnetic graphene oxide incorporated Fe3O4@polyaniline for the removal of bisphenol A, t-octyl-phenol, and α-naphthol from water
  • 本地全文:下载
  • 作者:Qingxiang Zhou ; Yuqin Wang ; Junping Xiao
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2017
  • 卷号:7
  • 期号:1
  • DOI:10.1038/s41598-017-11831-8
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:In this study, we fabricated a novel material composed of magnetic graphene oxide incorporated Fe3O4@polyaniline (Fe3O4@PANI-GO) using a modified Hummers' method, solvothermal, and two-step polymerisation method. The resulting products were characterised by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The results indicated that magnetic Fe3O4@PANI particles were successfully loaded onto the surface of the graphene oxide. Further Fe3O4@PANI-GO was investigated to remove bisphenol A(BPA), α-naphthol, and t-octyl-phenol (t-OP) from water samples by magnetic solid phase extraction. Under the optimal conditions, the Fe3O4@PANI-GO composite exhibited good adsorption capacity for t-OP, BPA, and α-naphthol, and the adsorption of these followed a pseudo-second-order kinetic model. Adsorption isotherms fit the Langmuir model, and the adsorption was an endothermic and spontaneous process. This work indicated that Fe3O4@PANI-GO earned great application prospect for removing phenolic contaminants from polluted water.
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