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  • 标题:A robust superhydrophobic TiO2 NPs coated cellulose sponge for highly efficient oil-water separation
  • 本地全文:下载
  • 作者:Hui Zhang ; Yuqi Li ; Zexiang Lu
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2017
  • 卷号:7
  • 期号:1
  • DOI:10.1038/s41598-017-09912-9
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:Oil-water separation has recently become a worldwide concern because of the increasing oil spill accidents and industrial oily wastewater generation. Herein, a facile method with the combined superhydrophobic coating and adhesive was used to fabricate superhydrophobic TiO2 NPs coated cellulose sponge. The developed materials exhibited excellent superhydrophobicity (WCA = 171°) and superoleophilicity (OCA = 0°), which can separate a variety of oil-water mixtures, including chloroform, toluene, kerosene and other contaminations. A high separation efficiency up to 98.5% for chloroform-water mixture was achieved when used for gravity-driven oil/water separation test. More importantly, the as-prepared samples exhibited excellent chemical stability and mechanical abrasion resistance even towards various corrosive oil/water mixtures (such as strong acid, alkali solution and salt-water environment) or a strong abrasion by aluminium oxide sandpaper of 600 mesh. In addition, the separation efficiency remained above 93% even after 40 scratch cycles, and the materials could be reused with a stable hydrophobicity, indicating a strong potential for industrial application.
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