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  • 标题:Study on novel structure of 4-amino-2-chloropyridine bis(salicylato)borate hydrate
  • 本地全文:下载
  • 作者:Yongmei Yan ; Haixing Liu ; Lintong Wang
  • 期刊名称:IOP Conference Series: Earth and Environmental Science
  • 印刷版ISSN:1755-1307
  • 电子版ISSN:1755-1315
  • 出版年度:2019
  • 卷号:300
  • 期号:5
  • 页码:1-6
  • DOI:10.1088/1755-1315/300/5/052004
  • 出版社:IOP Publishing
  • 摘要:A novel complex C14H8BO6. (C5H6ClN2). (H2O) has been synthesized from a hydrothermal reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction. Orthorhombic, Pccn. a=16.6736(13) Å, b=29.447(3) Å, c=8.1366(6) Å, α=β=γ=90°. V=3995.0(6) Å3. Z=8. R1 = 0.0567, wR2 = 0.1624, T=293(2)K. The B atom is coordinated by four O atoms from two salicylic acid molecular. The molecular structure stabilized by the O-H...O and O-H...N hydrogen-bonding interactions.
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