期刊名称：Journal of Materials and Environmental Science
印刷版ISSN：2028-2508
出版年度：2017
卷号：8
期号：s
页码：4778-4784
出版社：University of Mohammed Premier Oujda
摘要：The palladium(0) catalyzed substitution reactions of allylic acetates, carbonates andchlorides derivatives from demanding natural terpenic olefins by diethyl malonateanion has been performed under mild conditions. The protocol uses a catalytic amountof Pd(dba)2/PPh3 as promoting agent, providing new allyl products in good yields. Thereaction showed a highly regio- and stereoselectivity giving facile access to variousproducts of great industrial potential. The analysis of the optical activity of thesynthesized products has been discussed and gave some information on theintermediate complexes.
