This work introduces a novel modification of classical perturbation method (PM), denominated Optimized Distribution of Boundary Conditions Perturbation Method (ODBCPM) with the purpose to improve the performance of PM in the solution of ordinary differential equations (ODES). We will see that the main proposal of ODBCPM rests above all in the redistribution and optimization of the boundary conditions of the problem to be solved among the iterations of the proposed method. The solution of a couple of heat relevant problems indicates the potentiality of ODBCPM even for the case of large values of the perturbative parameter.