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  • 标题:The full nonrigid group theory for trimethylamine
  • 本地全文:下载
  • 作者:Masood Hamadanian ; Ali Reza Ashrafi
  • 期刊名称:International Journal of Mathematics and Mathematical Sciences
  • 印刷版ISSN:0161-1712
  • 电子版ISSN:1687-0425
  • 出版年度:2003
  • 卷号:2003
  • 期号:42
  • 页码:2701-2706
  • DOI:10.1155/S0161171203205159
  • 出版社:Hindawi Publishing Corporation
  • 摘要:

    The nonrigid molecule group theory (NRG) in which the dynamical symmetry operations are defined as physical operations is a new field in chemistry. Smeyers in a series of papers applied this notion to determine the character table of restricted NRG of some molecules. In this note, a simple method is described by means of which it is possible to calculate character tables for the symmetry group of molecules consisting of a number of methyl groups attached to a rigid framework. We study the full NRG of trimethylamine N ( CH 3 ) 3 and prove that it is a group of order 1296 with 28 conjugacy classes. The method can be generalized to apply to other nonrigid molecules. The full nonrigid (f-NRG) molecule group theory is seen to be used advantageously to study the internal dynamics of such molecules.

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