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  • 标题:Synthesis, physicochemical, thermal, computationand DNA binding evaluation of trans-[CuBr2(Me2NCH2CH2NH2)2] complex
  • 本地全文:下载
  • 作者:M. Abdoh ; R. Essa ; A. Sawafta
  • 期刊名称:Journal of Materials and Environmental Science
  • 印刷版ISSN:2028-2508
  • 出版年度:2018
  • 卷号:9
  • 期号:3
  • 页码:994-1003
  • DOI:10.26872/jmes.2018.9.3.114
  • 出版社:University of Mohammed Premier Oujda
  • 摘要:Asymmetrical Me2NCH2CH2NH2/copper(II)/bromide complex was synthesized in agood yield under ultrasonic vibration mode. The desired complex was characterizedusing, elemental EA, conductometric, UV-Vis, FTIR, MS and EDX analysis. Thethermal behaviour of the complex was performed by TG. DFT calculations in order toinvestigate the complex structure parameters. The absorption and viscosity titrationmeasurements reflected the desired complex as strong intercalate DNA-binder with highKb binding constant value.
  • 关键词:Copper(II);Spectral;DFT;Thermal;DNA binding
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