摘要：Nanocarbon materials are considered to be active for electrochemical oxygen reduction reaction (ORR) for hydrogen peroxide (H 2 O 2 ) synthesis. In the present work, a new type of fullerene 60 (C 60 )-carbon nanotubes (CNTs) hybrid with covalently attached C 60 onto outer surface of CNTs was synthesized. The structure of C 60 -CNT hybrid was confirmed by physical and chemical characterizations and its conformation is proposed featuring the covalent incorporation of CNTs and C 60 derivative. C 60 -CNT hybrid showed high efficiencies on electro-generating H 2 O 2 , owing to huge surface area and intermolecular electron-transfer in the hybrid structure. A high H 2 O 2 production rate of 4834.57 mg L -1 h -1 (426.58 mmol L -1 ) was achieved at - 0.2 V vs saturated calomel electrode (SCE).
