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  • 标题:Capacitive and Sensing Responses of Biomass Derived Silver Decorated Graphene
  • 本地全文:下载
  • 作者:Rabina Bhujel ; Sadhna Rai ; Khanindram Baruah
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2019
  • 卷号:9
  • 期号:1
  • 页码:1-14
  • DOI:10.1038/s41598-019-56178-4
  • 出版社:Springer Nature
  • 摘要:A new, easy and green method is utilized for producing silver decorated graphene for its application in sensors and supercapacitors. The biomass-derived silver decorated graphene (AgGr) samples are prepared using an APCVD reactor with varying the process temperature from 600 to 800 °C. The as-synthesized AgGr samples were then characterized by AFM, SEM, Raman spectroscopy, FTIR spectroscopy, XRD, cyclic voltammetry and impedance spectroscopy. The interlayer spacing and I D /I G ratio of the AgGr samples varied from 3.6 to 3.7 Å and 0.87 to 1.52, respectively, as the process temperature was raised from 600 to 800 °C. The SEM image shows the distribution of the flower-like structure of Ag flakes in the graphene sheet for the AgGr-800 sample. Also, the greater number of active sites on the surface of AgGr-800 and the presence of a higher number of defects makes it least useful for p-nitrophenol sensing due to the excess opening of the CV curve but has a maximum capacitance of 93.5 Fg -1 in 1 M H 2 SO 4 . AgGr-600 showed extremely good sensing of p-nitrophenol than the other AgGr samples. Therefore this novel technique can be utilized for the large scale manufacture of various metal decorated graphene samples for their application in different fields.
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