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  • 标题:Investigation on Electrochemical Performance of New Flexible Nanocomposite Poly(Vinylidene Fluoride-co-Hexafluoropropylene) Polymer Electrolytes
  • 本地全文:下载
  • 作者:G. Vijayakumar ; A. Maruthadurai ; R. Paramasivam
  • 期刊名称:International Journal of Polymer Science
  • 印刷版ISSN:1687-9422
  • 电子版ISSN:1687-9430
  • 出版年度:2020
  • 卷号:2020
  • 页码:1-8
  • DOI:10.1155/2020/3583806
  • 出版社:Hindawi Publishing Corporation
  • 摘要:This research paper as an article investigates electrochemical performance of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF- co -HFP) flexible nanocomposite polymer electrolytes which have been prepared successfully with incorporation of zinc oxide (ZnO) nanofiller. First, nanofillers are incorporated in a polymer matrix to form the flexible nanocomposite PVdF- co -HFP polymer membranes (PI-CMPM), and it is obtained by phase inversion technique. Contact angles of PI-CMPM have achieved a maximum of 136°. After this procedure, it has been activated by using a 1.0 M LiClO 4 containing of DMC/EC (1 : 1 v / v ratio) electrolyte solution to get flexible nanocomposite polymer electrolytes (PI-CMPE). The optimized PI-CMPM has increased the electrolyte uptake by 150%. It reaches the maximum ionic conductivity value of 2.47 × 10 − 3 S cm −1 at room temperature. Optimized PI-CMPE achieved a maximum transference number of 0.61, which may be further evidence for the ability to fabricate high-performance lithium ion polymer batteries.
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