摘要：Core Ideas An NMR‐based procedure was developed to determine adsorptive and capillary water contents. Capillary and adsorptive water contents had hysteretic behavior. The amount of adsorptive water was significant in all the tested soils. In analyzing the phase transition and water migration processes in multiphase porous systems, it is helpful to properly evaluate the unfrozen capillary water content and adsorptive water content, respectively. In this study, an innovative procedure was developed to determine the total, adsorptive, and capillary water contents in frozen soils based on the nuclear magnetic resonance (NMR) technique. We found a threshold value of the proton spin–spin relaxation time, T 2 , that separates the unfrozen pore water into two distinct regimes: the adsorptive regime for small T 2 values and the capillary regime for large T 2 values. We showed that the relationship between adsorptive (or capillary) water content and temperature is hysteretic for all three tested soils experiencing a freeze–thaw cycle. The hysteresis behavior of capillary or adsorptive water content during a freeze–thaw cycle is attributable to capillary effect, metastable nucleation, pore blocking, and variation of microstructure. In all the tested soils, the adsorptive water content was significantly larger than the capillary water content and was supported by the experimental evidence inferred from previous pore water potential measurements of various soils.
关键词：CPMG; Carr–Purcell–Meiboom–Gill; NMR; nuclear magnetic resonance; RF; radio frequency
