摘要：Core Ideas A surface complexation model for F − adsorption on soil was developed. Dissolved Al and Al–F complex adsorption added to the model better explained F − adsorption. The model can be extended to study the effect of existing co‐anions or humic substances. The adsorption processes of F − on a natural soil as a function of varying pH and F − concentration were evaluated by applying a surface complexation model (SCM) based on a single surface functional group with monodentate binding sites. A granitic soil from Tsukuba, Japan, was chosen as an example, and the SCM was developed to explain the pH dependency of F − sorption isotherms on the soil. Four possible surface complexation reactions were postulated with and without including dissolved Al. Optimized constants for F − surface complexation, and those for protonation and deprotonation, were used for the simulations. The SCM including dissolved Al and the adsorption of Al–F complex can simulate the experimental results, the decreasing trend of F − adsorption with the increase in pH, quite successfully. Also, including dissolved Al and the adsorption of Al–F complex to the model explained the change in solution pH after F − adsorption. Therefore, incorporation of dissolved Al and Al–F complex in model calculations of a soil–F system is an important improvement to predict F − concentrations of soil solutions.
关键词：BET; Brunauer; Emmett; Teller; CA; component additive; GC; general composite; IC; ion chromatography; ICP–MS; inductively coupled plasma mass spectrometry; IEP; isoelectric point; PZC; point of zero charge; SCM; surface complexation model; WMSE; weighted mean square error; XRD; X-ray diffractometry
