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  • 标题:Synthesis of cobalt doped mesoporous silica by using the rice husks as both silicon source and template with its catalytic oxidation of 2-methyl pyridine
  • 本地全文:下载
  • 作者:Zhongbiao Zhai ; Yingchun Miao ; Xie Gang
  • 期刊名称:E3S Web of Conferences
  • 印刷版ISSN:2267-1242
  • 电子版ISSN:2267-1242
  • 出版年度:2020
  • 卷号:189
  • 页码:1-6
  • DOI:10.1051/e3sconf/202018902022
  • 出版社:EDP Sciences
  • 摘要:Cobalt doped mesoporous silica (Co-SiO2) was prepared using the rice husks as both silicon source and template. Structural characterization of the catalysts was done by various techniques, such as Xray diffraction, FT-IR, N2 adsorption/desorption, and scanning electron microscopy. Co-SiO2 was used as a catalyst for the oxidation of 2-methyl pyridine and exhibited high substrate conversion (94.6%) and good product (2-pyridinecarboxylic acid) selectivity (92.4%). It even exhibited higher selectivity than Co-MTiO2, Co-MCM-41, Co-SBA-15. Fast hot catalyst filtration experiment proved that the catalyst acted as a heterogeneous one and it can be reused with almost the same activity.
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