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  • 标题:Formal Aerobic Oxidative Cross-Coupling of Benzofuranones with Azo Compounds Using Pd-μ-hydroxo Complex
  • 本地全文:下载
  • 作者:Rikako Ohnishi ; Masumi Sugawara ; Tetsuya Ezawa
  • 期刊名称:Chemical and Pharmaceutical Bulletin
  • 印刷版ISSN:0009-2363
  • 电子版ISSN:1347-5223
  • 出版年度:2020
  • 卷号:68
  • 期号:9
  • 页码:895-898
  • DOI:10.1248/cpb.c20-00359
  • 出版社:The Pharmaceutical Society of Japan
  • 摘要:We have developed a catalytic aerobic oxidative dimerization reaction of benzofuranones using a Pd(II)-µ-hydroxo complex.Radical-radical cross-coupling of the resulting dimers with azo compounds enabled the one-pot synthesis of structurally congested benzofuranones having two distinct vicinal all-carbon quaternary centers.
  • 关键词:palladium;molecular oxygen;radical;oxidative cross-coupling
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