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  • 标题:Study of Refractive Indices and Its Theories for Mixtures of N, N-Diethylethanamine and Acetates
  • 本地全文:下载
  • 作者:P. Tyagi ; K. Kumar ; M. Rani
  • 期刊名称:Journal of Scientific Research
  • 印刷版ISSN:2070-0237
  • 电子版ISSN:2070-0245
  • 出版年度:2020
  • 卷号:12
  • 期号:3
  • 页码:363-370
  • DOI:10.3329/jsr.v12i3.43717
  • 出版社:Rajshahi University
  • 摘要:This paper reports the refractive indices ( ) of N,N-diethylethanamine methyl acetate, ethyl acetate, propyl acetate, butyl acetate and pentyl acetate at 298.15 K and at different composition range. The various empirical correlations like Arago-Biot (AB), Gladstone-Dale (GD), Lorentz-Lorenz (L-L) Heller (H), Weiner (W), Newton (Nw) and Erying-John (E-J) were applied to experimental data for estimating theoretical value of refractive indices. For an equimolar mixture, the predicted deviation in refractive index values is consistent well with the experimental data. It has been found that the interactions between amine and different esters decrease when carbon chain length in ester increases. Also refractive indices are affected with change in temperature. To evaluate the standard deviation, RK polynomial equation was fitted to the measured refractive indices data.
  • 关键词:Refractive index; Triethylamine; Alkyl acetates; Correlations.
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