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  • 标题:Catalytic condensation of phenol with formaldehyde into BPF on recyclable anchoring sulfuric acid
  • 本地全文:下载
  • 作者:Hui Li ; Xi Cao ; Huiting He
  • 期刊名称:E3S Web of Conferences
  • 印刷版ISSN:2267-1242
  • 电子版ISSN:2267-1242
  • 出版年度:2020
  • 卷号:213
  • 页码:1-5
  • DOI:10.1051/e3sconf/202021301003
  • 出版社:EDP Sciences
  • 摘要:A novel solid-acid catalyst (PVC-EDA-SO4H) based on polyvinyl chloride (PVC) were prepared after amination of Ethylenediamine (EDA) and anchorage of sulfuric acid. The as-prepared catalyst was characterized by FT-IR, Element analysis, Chemical titration and Thermal analysis, the results indicated that the sulfuric acid was successfully anchored on PVC. The PVC-EDA-SO 4 H showed excellent catalytic performance for the synthesis of bisphenol F, and achieved almost high yield and selectivity (94%) of BPF under the mind reaction conditions. Meanwhile, exhibited excellent reusability without the significant loss after six cycles via simple filtration.
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