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  • 标题:Fluorinated Ketjen-black as Cathode Material for Lithium Primary Batteries
  • 其他标题:Fluorinated Ketjen-black as Cathode Material for Lithium Primary Batteries
  • 本地全文:下载
  • 作者:Shengbo Jiang ; Ping Huang ; Jiachun Lu
  • 期刊名称:E3S Web of Conferences
  • 印刷版ISSN:2267-1242
  • 电子版ISSN:2267-1242
  • 出版年度:2020
  • 卷号:218
  • 页码:2021
  • DOI:10.1051/e3sconf/202021802021
  • 出版社:EDP Sciences
  • 摘要:Lithium/fluorinated carbon (Li/CFx) batteries are the highest-energy-density primary batteries which are widely used in various field. Herein, the novel fluorinated carbon (CF x ) with superior performance are made of fluorination of ketjen-black. The fluorinated ketjen-black (F-KB) as the cathode material of Li/CF x delivered a high specific capacity over 880 mAh g -1 with a discharge plateau ~3.1 V (vs. Li /Li). The energy density over 2400 Wh kg -1 for F-KB is higher than the theoretical energy density (2180 Wh kg -1 ) of fluorinated graphite. F-KB can be discharged at high rate of 5C delivering a high-power density of 9710 W kg -1 with the energy density of 1610 Wh kg -1 , showing good performance of rate capability.
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