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  • 标题:Silver microsphere doping porous-carbon inspired shape-stable phase change material with excellent thermal properties: preparation, optimization, and mechanism
  • 本地全文:下载
  • 作者:Junwei Zhang ; Yan Chen ; Zeguang Nie
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2020
  • 卷号:10
  • 期号:1
  • 页码:1-14
  • DOI:10.1038/s41598-020-77901-6
  • 出版社:Springer Nature
  • 摘要:In this study, silver microspheres (SMS) were introduced into cotton stalk porous-carbon (CSP) to prepare silver microsphere doping porous-carbon (SMS-CSP), and then SMS-CSP was used as the matrix of polyethylene glycol (PEG) to synthesize shape-stable phase change material of PEG/SMS-CSP. It was found that the introduction of SMS into CSP could not only greatly improve the loading capacity of the porous-carbon for PEG, but also could increase the thermal conductivity of PEG/SMS-CSP. Additionally, the method of introducing SMS into porous-carbon had the advantages of environmental protection and simple operation. Moreover, the raw material of cotton stalk is a kind of agricultural waste, which has the merits of wide source, low price and easy to obtain. Furthermore, in the preparation of cotton stalk porous-carbon, with the increase of pyrolysis temperature the thermal conductivity of PEG/SMS-CSP could be enhanced significantly. The mechanism about the enhancement of thermal conductivity was clarified, which could provide more basic theory for the study about the thermal conductivity of shape-stable phase change materials (ss-PCMs) based on porous-carbon.
  • 其他摘要:Abstract In this study, silver microspheres (SMS) were introduced into cotton stalk porous-carbon (CSP) to prepare silver microsphere doping porous-carbon (SMS-CSP), and then SMS-CSP was used as the matrix of polyethylene glycol (PEG) to synthesize shape-stable phase change material of PEG/SMS-CSP. It was found that the introduction of SMS into CSP could not only greatly improve the loading capacity of the porous-carbon for PEG, but also could increase the thermal conductivity of PEG/SMS-CSP. Additionally, the method of introducing SMS into porous-carbon had the advantages of environmental protection and simple operation. Moreover, the raw material of cotton stalk is a kind of agricultural waste, which has the merits of wide source, low price and easy to obtain. Furthermore, in the preparation of cotton stalk porous-carbon, with the increase of pyrolysis temperature the thermal conductivity of PEG/SMS-CSP could be enhanced significantly. The mechanism about the enhancement of thermal conductivity was clarified, which could provide more basic theory for the study about the thermal conductivity of shape-stable phase change materials (ss-PCMs) based on porous-carbon.
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