期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2020
卷号：117
期号：23
页码：12686-12692
DOI：10.1073/pnas.2000128117
出版社：The National Academy of Sciences of the United States of America
摘要：Complete encapsulation of high-content sulfur in porous carbon is crucial for high performance Li−S batteries. To this end, unlike conventional approaches to control the pore of carbon hosts, we demonstrate controlling the interfacial energy of the solution in the process of penetrating the sulfur-dissolved solution. We unveil, experimentally and theoretically, that the interfacial energy with the carbon surface of the sulfur solution is the key to driving complete encapsulation of sulfur. In the infiltration of sulfur solutions with N -methyl-2-pyrrolidone, we achieve complete encapsulation of sulfur, even up to 85 wt %. The sulfur fully encapsulated cathode achieves markedly high volumetric capacity and stable cycle operation in its Li−S battery applications. We achieve a volumetric capacity of 855 mAh/cm 3 at 0.2C and a capacity reduction of 0.071% per cycle up to 300 cycles at 1C.
关键词：sulfur encapsulation ; interfacial energy ; lithium−sulfur batteries ; capillary action ; high sulfur loading
