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  • 标题:Acid hydrolysis of corn stover using hydrochloric acid: Kinetic modeling and statistical optimization
  • 本地全文:下载
  • 作者:Yong Sun ; Gang Yang ; Zhi-Hua Jia
  • 期刊名称:Chemical Industry and Chemical Engineering Quarterly
  • 印刷版ISSN:1451-9372
  • 出版年度:2014
  • 卷号:20
  • 期号:4
  • 页码:531-539
  • DOI:10.2298/CICEQ130911035S
  • 出版社:Association of the Chemical Engineers
  • 摘要:The hydrolysis of corn stover using hydrochloric acid was studied. The kinetic parameters of the mathematical models for predicting the yields of xylose, glucose, furfural and acetic acid were obtained, and the corresponding xylose generation activation energy of 100 kJ/mol was determined. The characterization of corn stover using with different techniques during hydrolysis indicated an effective removal of xylan and the slightly alteration on the structures of cellulose and lignin. A 23five levels Central Composite Design (CCD) was used to develop a statistical model for the optimization of process variables including acid concentration, pretreatment temperature and time. The optimum conditions determined by this model were found to be 108?C for 80 minutes with acid concentration of 5.8%. Under these conditions, the maximised results are the following: xylose 19.93 g/L, glucose 1.2 g/L, furfural 1.5 g/L, acetic acid 1.3 g/L. The validation of the model indicates a good agreement between the experimental results and the predicted values.
  • 关键词:hydrochloric acid; corn stover; kinetics; statistical modeling
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