期刊名称：Chemical Industry and Chemical Engineering Quarterly
印刷版ISSN：1451-9372
出版年度：2016
卷号：22
期号：2
页码：137-144
DOI：10.2298/CICEQ150618027M
出版社：Association of the Chemical Engineers
摘要：The kinetic model, which was originally developed for sunflower oil methanolysis catalyzed by CaO.ZnO, was examined for several other calcium-based catalysts like neat CaO, quicklime and Ca(OH)2. This model including triacylglycerols mass transfer- and chemically-controlled regimes demonstrated a good agreement with the experimental data in terms of a high coefficient of determination (0.971?0.022) and acceptable mean relative percentage deviation (?15.9%). Hence, this model is recommended for modeling the kinetics of sunflower oil methanolysis over calcium-based catalysts under widely ranging reaction conditions.
