期刊名称:Chemical Industry and Chemical Engineering Quarterly
印刷版ISSN:1451-9372
出版年度:2016
卷号:22
期号:1
页码:85-93
DOI:10.2298/CICEQ141001021L
出版社:Association of the Chemical Engineers
摘要:In this study, the mass transfer accompanied by an instantaneous irreversible chemical reaction in a slurry bubble column containing sparingly soluble fine reactant particles has been analyzed theoretically. Based on the penetration theory, combining the cell model, a one-dimensional mass transfer model was developed. In the model, the effects of the particle size and the particle dissolution near the gas-liquid interface on the mass transfer were taken into account. The mass transfer model was solved and an analytical expression of the time-mean mass transfer coefficient was attained. The reactive absorption of SO2from gas mixtures into Mg(OH)2/water slurry was investigated experimentally in a bubble column reactor to validate the mass transfer model. The results indicate that the present model has good predicting performance and could be used to predict mass transfer coefficient for the complicated gas-liquid-solid three-phase system with an instantaneous irreversible chemical reaction.