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  • 标题:Thermal Properties of Copolymers Based on Sugar
  • 本地全文:下载
  • 作者:I.R. Salagean ; M.C. Pascariu ; G. Bandur
  • 期刊名称:Universitatea Politehnica din Timisoara. Buletinul Stiintific. Seria Chimie si Ingineria Mediului
  • 印刷版ISSN:1224-6018
  • 出版年度:2009
  • 卷号:54(68)
  • 期号:02
  • 出版社:Universitatea Politehnica din Timisoara
  • 摘要:Carbohydrate based polymers have emerged as exciting topics of the polymer research, due to a worldwide focus on sustainable materials. The biodegradable polymers are indispensable in the modern society and their importance is continuously growing. We report here the characterization of a new class of biodegradable copolymers derived from monosaccharides.The glycomonomers 3- O -acryloyl-1,2:5,6-di- O -isopropylidene-α-glucofuranose (ADAG), and 1- O -acryloyl-2,3:5,6-di- O -isopropylidene-α-mannofuranose (ADAM), were co-polymerized with some acrylates and methacrylates, using as initiators benzoyl peroxide and lauroyl peroxide. The resulting copolymers were characterized by FT-IR, and the thermal stability of the copolymers was investigated using TG analysis, allowing a kinetic study of the degradation.
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