期刊名称:Universitatea Politehnica din Timisoara. Buletinul Stiintific. Seria Chimie si Ingineria Mediului
印刷版ISSN:1224-6018
出版年度:2009
卷号:54(68)
期号:02
出版社:Universitatea Politehnica din Timisoara
摘要:Carbohydrate based polymers have emerged as exciting topics of the polymer research, due to a worldwide focus on sustainable materials. The biodegradable polymers are indispensable in the modern society and their importance is continuously growing. We report here the characterization of a new class of biodegradable copolymers derived from monosaccharides.The glycomonomers 3- O -acryloyl-1,2:5,6-di- O -isopropylidene-α-glucofuranose (ADAG), and 1- O -acryloyl-2,3:5,6-di- O -isopropylidene-α-mannofuranose (ADAM), were co-polymerized with some acrylates and methacrylates, using as initiators benzoyl peroxide and lauroyl peroxide. The resulting copolymers were characterized by FT-IR, and the thermal stability of the copolymers was investigated using TG analysis, allowing a kinetic study of the degradation.