期刊名称:Universitatea Politehnica din Timisoara. Buletinul Stiintific. Seria Chimie si Ingineria Mediului
印刷版ISSN:1224-6018
出版年度:2005
卷号:50(64)
期号:01-02
出版社:Universitatea Politehnica din Timisoara
摘要:The new mononuclear complex [Cu(TAMEN)](ClO4)2 were TAMEN = N,N’-tetra(antipyryl-4-methyl)-1,2-diaminoethane was obtained and characterized by elemental analyses, electric conductivities, electronic and IR spectroscopy. The molar conductivities values of the copper(II) complex in DMF and DMSO solution demonstrate his behavior as 1:2 electrolytes type. Electronic spectra of the complex indicate the octahedral environment of the copper ion, whereas the infrared spectra for the complex support the coordination of TAMEN through the carbonylic oxygen atoms of the pyrazolone moiety and the amine nitrogen atoms of the 1,2- diaminoethane bridge.