期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：1982
卷号：79
期号：18
页码：5729-5733
DOI：10.1073/pnas.79.18.5729
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：In this last of three articles describing a two-fluid theory of liquid mixtures, the important result is a derivation of local compositions to describe nonrandomness (clustering) of mixing. The model is applied to the system methane/tetrafluoromethane. Although it appears that the two-fluid theory with local compositions may provide an improvement over random-mixing theories, it is likely that the use of local compositions overestimates the effect of nonrandomness.
