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  • 标题:Crystal structure of hexagonal MnAl4
  • 本地全文:下载
  • 作者:Linus Pauling
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1987
  • 卷号:84
  • 期号:11
  • 页码:3537-3539
  • DOI:10.1073/pnas.84.11.3537
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:A structure is proposed for the hexagonal form of MnAl4, with aH = 28.4 A and cH = 12.43 A, on the basis of a high-resolution electron micrograph and comparison with crystals of known structures. The proposed structure involves seven 104-atom complexes of 20 Friauf polyhedra, sharing some atoms with one another. It is closely related to the 23.36-A cubic structure of MnAl4 and to the 14.19-A cubic structure of Mg32(Al,Zn)49.
  • 关键词:icosahedral metal complexes ; Friauf polyhedra
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