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  • 标题:Structures of the Visual Chromophores and Related Pigments: A Conformational Basis of Visual Excitation
  • 本地全文:下载
  • 作者:M. Sundaralingam ; C. Beddell
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1972
  • 卷号:69
  • 期号:6
  • 页码:1569-1573
  • DOI:10.1073/pnas.69.6.1569
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:A detailed conformational analysis of the known crystal structures of vitamin A, carotenoid, and xanthenoid derivatives has been made. These studies suggest that the visual chromophore 11-cis retinal and its isomers may each occur in several different conformational states, which would be expected to have different lightabsorbing characteristics. The presence of such states for 11-cis retinal and all-trans retinal may contribute to the observed rhodopsin intermediates that have been characterized by different {lambda}max values, and to the breadth of spectral response in scotopic and color vision.
  • 关键词:11- cis retinal ; vitamin A ; xanthenoid ; crystal structure ; carotenoid
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