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  • 标题:Uncoupling of local field spectra in nuclear magnetic resonance: determination of atomic positions in solids
  • 本地全文:下载
  • 作者:J S Waugh
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1976
  • 卷号:73
  • 期号:5
  • 页码:1394-1397
  • DOI:10.1073/pnas.73.5.1394
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:Solid state nuclear magnetic resonance as a method of determining crystal structure has had limited success. Three distinct reasons for this failure can be identified when the resonance spectrum is of a dilute spin species in the presence of another abundant species. Two of these difficulties, and in part the third, can be mitigated by a family of coherent averaging techniques in double resonance, with considerably improved prospects for locating the rare spins with respect to their nearby neighbors. A particularly advantageous procedure is described and possible applications are discussed.
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