期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：1976
卷号：73
期号：8
页码：2533-2535
DOI：10.1073/pnas.73.8.2533
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：The purpose of this paper has been to investigate the effect of solvent on radiationless transitions. Two types of the solvent effect have been studied: one is the so-called medium-induced radiationless transition, i.e., the radiationless transition induced by the interaction between the solute and solvent, and the other is the effect of solvent on the radiationless transition through the change in energy gap induced by the solute-solvent interaction.
关键词：electronic relaxation ; Fermi golden rule ; energy gap shift ; blue shift ; red shift
