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  • 标题:Conductivity and structure of bilinear organic addition compounds
  • 本地全文:下载
  • 作者:J. C. Phillips
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1976
  • 卷号:73
  • 期号:11
  • 页码:3820-3824
  • DOI:10.1073/pnas.73.11.3820
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:The relationship between crystal structures and metallic conductivities of linear organic materials such as tetrathiafulvalene-tetracyanoquinodimethane is explained in terms of strong lateral elastic interactions between chains. A microdomain model is presented in which at high temperatures there are, in general, two coexisting phases on each stacked molecular chain. The ordering of (in general, four) phases on two interacting chains leads to a variety of phase transitions at low temperatures. By examining temperature-dependent electrical conductivities and magnetic susceptibilities one can establish the character of each such transition.
  • 关键词:microdomains ; coexisting phases ; Martensitic transformations
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