The effect of the density of environmental samples on the counting efficiency of Ge detectors used in gamma-spectrometry was studied. The dependence εff(ρ) was determined for two HPGe detectors (relative efficiencies 18% and 20%) using five radioactive standard reference materials (silicone resins, epoxy resin, milk powder, soil) with different matrix densities (0.45-1.22 g/cm3) in Marinelli beakers (V = 500 cm3). The dependence of efficiency vs. density was found to be linear and the regression parameters for energies in the range of 60-2000 keV were determined, too. The effect of variation in density on the counting efficiency of Ge detectors is dominant in the range of lower energies (60-600 keV) and de creases with energies in the higher energy range.