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  • 标题:Decoloration of Acid Red 88 Using Synthetic-Zeolite-Based Iron as a Heterogeneous Photo-Fenton Catalyst
  • 本地全文:下载
  • 作者:Seiichirou Ohura ; Hiroyuki Harada ; Masahiko Shiki
  • 期刊名称:Environment and Pollution
  • 印刷版ISSN:1927-0909
  • 电子版ISSN:1927-0917
  • 出版年度:2012
  • 卷号:2
  • 期号:1
  • 页码:36
  • DOI:10.5539/ep.v2n1p36
  • 语种:English
  • 出版社:Canadian Center of Science and Education
  • 摘要:Decoloration and mineralization of an azo dye, Acid Red 88, were conducted using synthetic-zeolite-based Fe as a heterogeneous photo-Fenton catalyst in the presence of ultraviolet (UV) rays and H 2 O 2 . Under the optimal conditions (pH = 5.5, 17.6 mM H 2 O 2 , and 4 W m - 2 UVC), 100% decoloration and 90% total organic carbon removal of 0.12 mM Acid Red 88 were achieved in 120 min. The effects of initial pH with time, as well as oxidation, were studied in a batch reactor. It was found that high decoloration was achieved using a heterogeneous Fenton method at pH 7 and lower. The catalyst also had the advantages of low leaching of Fe 3+ ions and maintenance of a high decoloration in consecutive catalytic treatments. Zeolite-based Fe was successfully used repeatedly (up to three consecutive cycles) for decoloration. A high rate of decoloration was also achieved in the case of continuous operation, although <=0.4 mg L -1 of Fe were leached into the treated water.
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