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  • 标题:SPECTROSCOPIC AND BIOLOGICAL STUDIES OF SOME NEW COORDINATION COMPOUNDS OF TIN (II) AND (IV) WITH SEMICARBAZONES AND THIOSEMICARBAZONES.
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  • 作者:JITENDRA KUMAR RAWAT ; HARI SHANKAR YADAV ; A.K. VARSHNEY
  • 期刊名称:Indian Streams Research Journal
  • 印刷版ISSN:2230-7850
  • 出版年度:2012
  • 卷号:II
  • 期号:II
  • 出版社:Indian Streams Research Journal
  • 摘要:The present paper is a report on the synthesis of some new tin (II) and tin (IV) complexes by the reaction of stannous chloride and dimethyltin dichloride with semicarbazones and thiosemicarbazones using tetrahydrofuran(THF) as reaction medium. Semicarbazones and thiosemicarbazones used in these studies are synthesized by the condensation of 1-acetyl-2-naphthol, 2-acetyl-1-naphathol, 2-acetyl-5-methyl furan, 2-acetyl-4-methyl thiophene and 2-acetyl-naphthalene with semicarbazide/ thiosemicarbazide. The bonding pattern and geometry of tin complexes are characterized by spectroscopic evidences. The ligands and their metal complexes have been screened for antitubercular, antibacterial and antifungal activities and are found quite active in this respect. Plant growth activity has also been evaluated and is found negative growth.
  • 关键词:semicarbazones; ; ; ;thiosemicarbazones;antibacterial activities;spectroscopic evidence
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