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  • 标题:Anaerobic Biotransformation of Nitro-Compounds to Amines by Bovine Rumen Fluid
  • 本地全文:下载
  • 作者:Alfonso Rodríguez ; Ignacio Irazoqui ; Guzmán Álvarez
  • 期刊名称:Green and Sustainable Chemistry
  • 印刷版ISSN:2160-6951
  • 电子版ISSN:2160-696X
  • 出版年度:2011
  • 卷号:1
  • 期号:3
  • 页码:47-53
  • DOI:10.4236/gsc.2011.13009
  • 出版社:Scientific Research Publishing
  • 摘要:Microorganims of the bovine rumen fluid biocatalyzed the reduction of nitro-compound substrates to yield the respective amines. This enzymatic process, using ruminal contents, has rarely been reported in associa- tion with the bioreduction of nitro groups. The biotransformation reactions catalyzed by this system were de- pendent of both the electronic characteristics and the area/volume of the nitro-substrates confirming the processes are enzymatic. The semi-preparative scale biotransformation went by in good yield showing the rumen fluid may be employed in the synthesis of amines under very mild conditions and, moreover, it may have application in the bioremediation of nitro-compounds.
  • 关键词:Biotransformation; Nitro-Compounds; Amines; Rumen; Ruminal Fluid; Bovine
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