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  • 标题:Styrene Epoxidation in Aqueous over Triazine-Based Microporous Polymeric Network as a Metal-Free Catalyst
  • 本地全文:下载
  • 作者:Mohd Bismillah Ansari ; Eun-Young Jeong ; Sang-Eon Park
  • 期刊名称:Green and Sustainable Chemistry
  • 印刷版ISSN:2160-6951
  • 电子版ISSN:2160-696X
  • 出版年度:2012
  • 卷号:2
  • 期号:1
  • 页码:1-7
  • DOI:10.4236/gsc.2012.21001
  • 出版社:Scientific Research Publishing
  • 摘要:Tirazine based microporous polymeric (TMP) network was found to be an efficient metal-free catalyst for the epoxidation of styrene. The reactions were performed in water as an environmentally benign medium using H2O2 as a green oxidant at ambient temperature. The reaction afforded higher yield with 90% conversion of styrene and 98% selectivity to styrene oxide in 6 h. The triazine based microporous polymeric network can be readily recovered and reused up to 4 cycles without significant loss in catalytic activity and selectivity.
  • 关键词:Triazine Microporous Polydendritic Network; Metal-Free Catalyst; Aqueous Medium; Epoxidation; Styrene
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