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  • 标题:Copper Zinc Sulfur Compound Solar Cells Fabricated by Spray Pyrolysis Deposition for Solar Cells
  • 本地全文:下载
  • 作者:Noriyuki Kitagawa ; Seigo Ito ; Duy-Cuong Nguyen
  • 期刊名称:Natural Resources
  • 印刷版ISSN:2158-706X
  • 电子版ISSN:2158-7086
  • 出版年度:2013
  • 卷号:4
  • 期号:1A
  • 页码:142-145
  • DOI:10.4236/nr.2013.41A018
  • 出版社:Scientific Research Publishing
  • 摘要:Cu-Zn-S (CZS) films were deposited by the spray pyrolysis method. As-deposited CZS film showed a low crystallinity. The resistivity of CZS film with Cu/(Cu+Zn) ratio of 50% is around 10-2Ω﹒cm. The CZS film elements using spray Cu-Zn (=1:1) solution with thiourea was confirmed as  Cu:Zn:Sn=2:2:3 by ICP-MS and EDX. The band gap of CZS films was varied in the range of 1.8 - 3.5 ev when the  Cu/(Cu+Zn)ratio was increased from 0 to 67%; CZS film with Cu/(Cu+Zn)ratio of 50 % showed an wide band gap of 2 eV. The photovoltaic characteristics were confirmed with cell structure of . The best cell was observed at the CZS films with Cu/(Cu+Zn)ratio of 50%; these cells depicted a conversion efficiency of 1.7%.
  • 关键词:Cu2Zn2S3; Spray Pyrolysis; Solar Cells; Superstrate Structure; TiO2
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