标题：Synthesis, Spectral and Structural Charcterization of Novel Dichloro-Ruthenium(II)/triphenylphos phine/(3,4-diaminophenyl)(phenyl)methanone Complex,
期刊名称：Journal of Materials and Environmental Science
印刷版ISSN：2028-2508
出版年度：2013
卷号：4
期号：5
页码：822-827
出版社：University of Mohammed Premier Oujda
摘要：The novel trans-[Cl2Ru(II)(PPh3)2(3,4-diaminophenyl)(phenyl)methanone]complex was obtained by reacting RuCl2(PPh3)3 with equimolar amounts of (3,4-diaminophenyl)(phenyl)methanone as diamine co-ligand in CH2Cl2. One of the PPh3ligand was quantitatively exchanged by (3,4-diaminophenyl)(phenyl)methanone, even when excess diamine was added. The trans-RuCl2desired complex was characterized on the basis of elemental analysis, elemental analysis, FAB-MS, IR, UV-vis, 1H, 13C and 31P{1H}NMR
