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  • 标题:Enhancement of Cadmium and Zinc Flame Spectrometric Signals by Using APDTC-nButylamine-MIBK Extractants
  • 本地全文:下载
  • 作者:Tan Wee Tee ; Wong See Keong
  • 期刊名称:Pertanika Journal of Social Sciences & Humanities
  • 印刷版ISSN:0128-7702
  • 电子版ISSN:2231-8534
  • 出版年度:1991
  • 卷号:14
  • 期号:1
  • 出版社:Universiti Putra Malaysia
  • 摘要:Ammonium pyrrolidine-dithiocarbamate (APDTC) and methyl-isobutyl-ketone (MIBK) extractant were found to be considerably improved by the addition of nbutylamine especially for the chemical analysis of Cd(II) and Zn(II) ions. Solvent extraction of the bivalent metal ions is a function of pH and the concentration of APDTC and nbutylamine. Cd(II) and Zn(II) ions exhibit considerable flame spectrometric signal enhancement for pH ranges from 7 to 12 and 2 to 12 respectively when APDTC-nbutylamine-MIBK was used as the extractant in place of APDTC-MIBK. The signal enhancement observed may be interpreted in terms of the formation of synergistic amine adduct and/or mixed solvent effect
  • 关键词:Signal enhancement; cadmium; zinc; solvent extraction; nbutylamine; APDTC; MIBK
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